Thermal sampling compensation law processes explained through a structure dependent relaxation time

被引：6

作者：

Ferreira, GFL

机构：

[1] Inst. de Fisica de São Carlos, Universidade de São Paulo, 13560-970, São Carlos SP

来源：

JOURNAL OF ELECTROSTATICS | 1996年 / 36卷 / 04期

关键词：

polymers; dielectric relaxation; compensation law; dielectric spectroscopy; activation energy; thermal sampling; polarization;

D O I：

10.1016/0304-3886(95)00053-4

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

Thermal sampling technique in polymers near T-g has disclosed processes obeying a compensation law. It is shown that a distributed process with a single relaxation time having a structure dependent activation energy through coupling with free volume changes, ever occurring at T-g, may explain the observed compensation laws.

引用

页码：323 / 330

页数：8