Hydrosilation of polyfluoroolefin in dense carbon dioxide

被引：15

作者：

He, LN ^{[1
]}

Choi, JC ^{[1
]}

Sakakura, T ^{[1
]}

机构：

[1] Natl Inst Mat & Chem Res, Tsukuba, Ibaraki 3058565, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 11期

关键词：

hydrosilation; olefin; carbon dioxide; ruthenium; rhodium;

D O I：

10.1016/S0040-4039(01)00126-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ruthenium and rhodium phosphine complexes catalyze the hydrosilation of olefins in dense carbon dioxide. The incorporation of polyfluorinated phosphine ligands in the conventional hydrosilation catalysts provides enhanced solubility in dense carbon dioxide resulting in a higher catalytic activity and selectivity; the best result was obtained using RuCl2[P(C6H4-p-CF3)(3)](3). The reaction is applicable to the synthesis of a fluorous silane coupling agent. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2169 / 2171

页数：3

共 15 条

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