The influence of disorder on the magnetic phenomena in metalloporphyrin-based magnets

被引：22

作者：

Girtu, MA

Wynn, CM

Sugiura, KI

Miller, JS

Epstein, AJ

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

[2] OHIO STATE UNIV,DEPT CHEM,COLUMBUS,OH 43210

来源：

SYNTHETIC METALS | 1997年 / 85卷 / 1-3期

关键词：

magnetic measurements; magnetic phase transitions;

D O I：

10.1016/S0379-6779(97)80402-X

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We investigate the effects of disorder in the quasi-one-dimensional metalloporphyrin family of molecule-based magnets. These materials are electron transfer salts consisting of linear chains of alternating S=2 Mn-III-porphyrin donors and S=1/2 bridging accepters. Studies of the irreversibilities, and frequency dependence of the ac magnetic susceptibility suggest a cluster glass-like behavior in certain compounds at low temperatures. The role of the intercalated solvent and its relation to any disorder present in the compounds are discussed.

引用

页码：1703 / 1704

页数：2

共 7 条

[1] MAGNETIC-BEHAVIOR OF OCTAETHYLPORPHYRINATOMANGANESE(III) TETRACYANOETHENIDE, [MNOEP][TCNE], AND HEXACYANOBUTADIENIDE, [MNOEP][C-4(CN)(6)] - THE IMPORTANCE OF A UNIFORM CHAIN FOR STABILIZING STRONG EFFECTIVE FERROMAGNETIC COUPLING [J].