Crystal Engineering of a Microporous, Catalytically Active fcu Topology MOF Using a Custom-Designed Metalloporphyrin Linker

被引：150

作者：

Meng, Le ^{[1
]}

Cheng, Qigan ^{[1
]}

Kim, Chungsik ^{[1
]}

Gao, Wen-Yang ^{[1
]}

Wojtas, Lukasz ^{[1
]}

Chen, Yu-Sheng ^{[2
]}

Zaworotko, Michael J. ^{[1
]}

Zhang, X. Peter ^{[1
]}

Ma, Shengqian ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[2] Univ Chicago, ChemMatCARS, Ctr Adv Radiat Sources, Argonne, IL 60439 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 40期

基金：

美国国家科学基金会;

关键词：

cobalt; crystal engineering; heterogeneous catalysis; metalloporphyrins; Metal-organic frameworks; METAL-ORGANIC FRAMEWORK; CAGES; EPOXIDATION; STORAGE; ADSORPTION; CATALYST; SYNTHONS;

D O I：

10.1002/anie.201205603

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A 12-connected fcu metal-organic framework (MOF), MMPF-3, has been prepared using a Co II metalloporphyrin. MMPF-3 is comprised of the same polyhedral supermolecular building blocks as the prototypal fcu-MOF, fcu-MOF-1, and its nanoscale cavities feature 18 catalytically active cobalt centers. The high density (ca. 5 cobalt sites/nm 3) affords MMPF-3 superior performance in catalytic epoxidation of trans-stilbene compared to other MOFs. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10082 / 10085

页数：4

共 90 条

[1]

Andrews M. B., 2012, ANGEW CHEM, V124, P6735

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