Electron transfer by copper centers

被引：394

作者：

Rorabacher, DB ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 02期

关键词：

D O I：

10.1021/cr020630e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The influence of coordination geometry upon the thermodynamic potentials and electron-transfer kinetics for Cu(II/I) systems involving a single copper center was examined. The electron-transfer reactions involving Cu(III/II) were also studied. Several electron-transfer studies on blue copper proteins were also examined. The factors affecting the magnitude of the copper (II/I) self-exchange rate constants were also analyzed. The applicability of the Marcus relationship to copper (II/I) systems was also described.

引用

收藏

页码：651 / 697

页数：47

相关论文

共 217 条

[1] IS LIGAND TOPOLOGY AN INFLUENCE ON THE REDOX POTENTIALS OF COPPER-COMPLEXES [J].

ADDISON, AW .

INORGANICA CHIMICA ACTA, 1989, 162 (02) :217-220

[2]

ADMAN ET, 1989, J BIOL CHEM, V264, P87

[3]

ADMAN ET, 1985, TOPICS MOL STRUCTU 1, P1

[4] THE LOW-TEMPERATURE CRYSTAL-STRUCTURE (203-K AND 123-K) AND ELECTRONIC-PROPERTIES OF DIAMMONIUM HEXA-AQUACOPPER(II) DISULFATE - A FLUXIONAL CUO6 CHROMOPHORE [J].

ALCOCK, NW ;

DUGGAN, M ;

MURRAY, A ;

TYAGI, S ;

HATHAWAY, BJ ;

HEWAT, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (01) :7-14

[5] REDOX CHEMISTRY OF BIS(2,9-DIMETHYL-4,7-BIS(SULFONATOPHENYL)-1,10-PHENANTHROLINATO)COPPER(II/I) - REACTIONS WITH NICKEL OXIME IMINE COMPLEXES [J].

ALLAN, AE ;

LAPPIN, AG ;

LARANJEIRA, MCM .

INORGANIC CHEMISTRY, 1984, 23 (04) :477-482

[6] INFLUENCE OF COORDINATION-NUMBER ON COPPER(I)-COPPER(II) REDOX INTERCONVERSIONS .2. FE(CN)64- REDUCTION OF A STERICALLY CONSTRAINED BIS(SUBSTITUTED PHENANTHROLINE) COMPLEX OF COPPER(II) IN AQUEOUS-SOLUTION [J].

ALSHATTI, N ;

LAPPIN, AG ;

SYKES, AG .

INORGANIC CHEMISTRY, 1981, 20 (05) :1466-1469

[7] ELECTRON-TRANSFER REACTIONS OF TRIS(1,10-PHENANTHROLINE)COBALT(II) WITH COPPER(III) IMINE OXIME COMPLEXES [J].

ALSOGAIR, FM ;

SULFAB, Y .

TRANSITION METAL CHEMISTRY, 1993, 18 (01) :19-22

[8] Electron-transfer kinetics of copper(II/I) tripodal ligand complexes [J].

Ambundo, EA ;

Yu, QY ;

Ochrymowycz, LA ;

Rorabacher, DB .

INORGANIC CHEMISTRY, 2003, 42 (17) :5267-5273

[9] Influence of coordination geometry upon copper(II/I) redox potentials. Physical parameters for twelve copper tripodal ligand complexes [J].

Ambundo, EA ;

Deydier, MV ;

Grall, AJ ;

Aguera-Vega, N ;

Dressel, LT ;

Cooper, TH ;

Heeg, MJ ;

Ochrymowycz, LA ;

Rorabacher, DB .

INORGANIC CHEMISTRY, 1999, 38 (19) :4233-4242

[10] Electron-transfer kinetics of tris(2-(methylthioethyl))aminecopper(II/I).: A tripodal ligand complex exhibiting virtual C3v symmetry [J].

Ambundo, EA ;

Ochrymowycz, LA ;

Rorabacher, DB .

INORGANIC CHEMISTRY, 2001, 40 (20) :5133-5138

← 1 2 3 4 5 6 7 8 9 10 →