Electron transfer by copper centers

被引：394

作者：

Rorabacher, DB ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 02期

关键词：

D O I：

10.1021/cr020630e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The influence of coordination geometry upon the thermodynamic potentials and electron-transfer kinetics for Cu(II/I) systems involving a single copper center was examined. The electron-transfer reactions involving Cu(III/II) were also studied. Several electron-transfer studies on blue copper proteins were also examined. The factors affecting the magnitude of the copper (II/I) self-exchange rate constants were also analyzed. The applicability of the Marcus relationship to copper (II/I) systems was also described.

引用

收藏

页码：651 / 697

页数：47

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