Insertion of carbon dioxide into (PCP)PdII-Me bonds

被引：74

作者：

Johansson, R ^{[1
]}

Jarenmark, M ^{[1
]}

Wendt, OF ^{[1
]}

机构：

[1] Lund Univ, Dept Chem, S-22100 Lund, Sweden

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 19期

关键词：

D O I：

10.1021/om0505561

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd-Me bond. It is reactive toward CO2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe2, and catalytic carboxylation is possible in benzene.

引用

页码：4500 / 4502

页数：3

共 33 条

[31] Recent developments in the activation of carbon dioxide by metal complexes [J].