Lithiosilanes and their application to the synthesis of polysilane dendrimers

被引：132

作者：

Sekiguchi, A ^{[1
]}

Lee, VY ^{[1
]}

Nanjo, M ^{[1
]}

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

来源：

COORDINATION CHEMISTRY REVIEWS | 2000年 / 210卷

关键词：

silicon derivatives; silyllithium compounds; group I metals; dendrimer; polysilane;

D O I：

10.1016/S0010-8545(00)00315-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An account is given of the preparation and structural investigations of silyllithium compounds, including X-ray and NMR data. This review covers the chemistry of lithiosilanes with alkyl, aryl, functional substituents and lithiooligosilanes with Si-Si bonds. Application of lithiosilanes for the synthesis of polysilane dendritic molecules is also described. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：11 / 45

页数：35

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