Lithiosilanes and their application to the synthesis of polysilane dendrimers

被引：132

作者：

Sekiguchi, A ^{[1
]}

Lee, VY ^{[1
]}

Nanjo, M ^{[1
]}

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

来源：

COORDINATION CHEMISTRY REVIEWS | 2000年 / 210卷

关键词：

silicon derivatives; silyllithium compounds; group I metals; dendrimer; polysilane;

D O I：

10.1016/S0010-8545(00)00315-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An account is given of the preparation and structural investigations of silyllithium compounds, including X-ray and NMR data. This review covers the chemistry of lithiosilanes with alkyl, aryl, functional substituents and lithiooligosilanes with Si-Si bonds. Application of lithiosilanes for the synthesis of polysilane dendritic molecules is also described. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：11 / 45

页数：35

共 139 条

[71] Synthesis and crystal structure of a nanometer-scale dendritic polysilane [J].

Lambert, JB ;

Wu, HW .

ORGANOMETALLICS, 1998, 17 (22) :4904-4909

[72] Two-dimensional silicon-29 inadequate as a structural tool for branched and dendritic polysilanes [J].

Lambert, JB ;

Basso, E ;

Qing, N ;

Lim, SH ;

Pflug, JL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 554 (02) :113-116

[73] DIASTEREOTOPIC GROUPS IN SILYL-LITHIUM AND GERMYL-LITHIUM COMPOUNDS - SLOW INVERSION ABOUT SILICON AND GERMANIUM [J].

LAMBERT, JB ;

URDANETAPEREZ, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (01) :157-162

[74] First-generation dendritic polysilanes [J].

Lambert, JB ;

Pflug, JL ;

Denari, JM .

ORGANOMETALLICS, 1996, 15 (02) :615-625

[75] SYNTHESIS AND STRUCTURE OF A DENDRITIC POLYSILANE [J].

LAMBERT, JB ;

PFLUG, JL ;

STERN, CL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (01) :98-99

[76]

Lickiss PD, 1995, COORDIN CHEM REV, V145, P75

[77]

Majoral JP, 1998, TOP CURR CHEM, V197, P79

[78] Dendrimers containing heteroatoms (Si, P, B, Ge, or Bi) [J].

Majoral, JP ;

Caminade, AM .

CHEMICAL REVIEWS, 1999, 99 (03) :845-880

[79]

MATHIAS LJ, 1995, ADV DENDR MACROMOL, V2, P101

[80] SONOCHEMICAL SYNTHESIS OF POLYSILYLENES BY REDUCTIVE COUPLING OF DISUBSTITUTED DICHLOROSILANES WITH ALKALI-METALS [J].

MATYJASZEWSKI, K ;

GRESZTA, D ;

HRKACH, JS ;

KIM, HK .

MACROMOLECULES, 1995, 28 (01) :59-72

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