Highly active Au/TiO2 catalysts for low-temperature CO oxidation:: preparation, conditioning and stability

被引:162
作者
Schumacher, B
Plzak, V
Kinne, M
Behm, RJ
机构
[1] Ctr Solar Energy & Hydrogen Res, D-89081 Ulm, Germany
[2] Univ Ulm, Dept Surface Chem & Catalysis, D-89069 Ulm, Germany
关键词
supported catalyst; catalyst activation; catalyst deactivation; CO oxidation; selective CO oxidation; particle size; Au/TiO2; TEM; DRIFTS; XPS; XRD; kinetic measurements;
D O I
10.1023/A:1024731812974
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Using a modified deposition-precipitation procedure and a new reductive conditioning method, Au/TiO2 catalysts with small metallic Au particles(<2 nm) and a very high activity for low-temperature CO oxidation were prepared. The particles are stable during reaction; a decreasing activity is caused by the accumulation of by-products on the catalyst.
引用
收藏
页码:109 / 114
页数:6
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