Magnetic field effects on the photoinduced electron transfer of 10-methylphenothiazine with 4-(4-cyanobenzoyloxy) TEMPO in fluid solutions

被引:33
作者
Mori, Y [1 ]
Sakaguchi, Y [1 ]
Hayashi, H [1 ]
机构
[1] RIKEN, Inst Phys & Chem Res, Mol Photochem Lab, Wako, Saitama 35101, Japan
关键词
D O I
10.1016/S0009-2614(98)00050-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Magnetic field effects on both the quenching of the tripler excited state of 10-methylphenothiazine (S = 1) with 4-(4-cyanobenzoyloxy)TEMPO (S = 1/2) and the dynamic behavior of generated radical ion pairs (S = 1/2 and 3/2) were directly observed by a nanosecond laser photolysis technique, in 2-propanol, with increasing field from 0 T to 2 T, the quenching rate was decreased by (11.8 +/- 1.2)% and the yield of the escaped cation radical was increased by (90 +/- 8)%. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:446 / 451
页数:6
相关论文
共 14 条
[1]   MAGNETIC-FIELD EFFECTS ON CHEMILUMINESCENT FLUID SOLUTIONS [J].
ATKINS, PW ;
EVANS, GT .
MOLECULAR PHYSICS, 1975, 29 (03) :921-935
[2]   ELECTROGENERATED CHEMILUMINESCENCE .7. INFLUENCE OF AN EXTERNAL MAGNETIC-FIELD ON LUMINESCENCE INTENSITY [J].
FAULKNER, LR ;
BARD, AJ ;
TACHIKAWA, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (03) :691-+
[3]  
FUJIWARA Y, 1989, CHEM PHYS LETT, V155, P157
[4]  
HAYASHI H, 1990, LASERS POLYM SCI TEC, V2, P1
[5]  
HAYASHI H, 1990, PHOTOCHEM PHOTOBIOL, V1, P59
[6]   EFFECTS OF LARGE MAGNETIC-FIELDS ON THE DYNAMIC BEHAVIOR OF RADICAL-ION PAIRS IN A NON-VISCOUS SOLUTION AT ROOM-TEMPERATURE [J].
IGARASHI, M ;
SAKAGUCHI, Y ;
HAYASHI, H .
CHEMICAL PHYSICS LETTERS, 1995, 243 (5-6) :545-551
[7]   EFFECTS OF MAGNETIC FIELDS ON MUTUAL ANNIHILATION OF TRIPLET EXCITONS IN ANTHRACENE CRYSTALS [J].
JOHNSON, RC ;
MERRIFIE.RE .
PHYSICAL REVIEW B-SOLID STATE, 1970, 1 (02) :896-+
[8]   LIGHT-INITIATED ELECTRON-TRANSFER IN FUNCTIONAL SURFACTANT ASSEMBLIES .1. MICELLES WITH TRANSITION-METAL COUNTERIONS [J].
MOROI, Y ;
BRAUN, AM ;
GRATZEL, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (03) :567-572
[9]   MAGNETIC-FIELD EFFECTS ON THE PHOTODISSOCIATION REACTION OF TRIPHENYLPHOSPHINE IN NON-VISCOUS HOMOGENEOUS SOLUTIONS [J].
SAKAGUCHI, Y ;
HAYASHI, H .
CHEMICAL PHYSICS LETTERS, 1995, 245 (06) :591-597
[10]   Magnetic field effects on the photochemical electron-transfer reactions of 10-methylphenothiazine and dicyanobenzene derivatives in nonviscous homogeneous solutions [J].
Sakaguchi, Y ;
Hayashi, H .
JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (04) :549-555