Magnetic field effects on the photoinduced electron transfer of 10-methylphenothiazine with 4-(4-cyanobenzoyloxy) TEMPO in fluid solutions

被引：33

作者：

Mori, Y ^{[1
]}

Sakaguchi, Y ^{[1
]}

Hayashi, H ^{[1
]}

机构：

[1] RIKEN, Inst Phys & Chem Res, Mol Photochem Lab, Wako, Saitama 35101, Japan

来源：

CHEMICAL PHYSICS LETTERS | 1998年 / 286卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(98)00050-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Magnetic field effects on both the quenching of the tripler excited state of 10-methylphenothiazine (S = 1) with 4-(4-cyanobenzoyloxy)TEMPO (S = 1/2) and the dynamic behavior of generated radical ion pairs (S = 1/2 and 3/2) were directly observed by a nanosecond laser photolysis technique, in 2-propanol, with increasing field from 0 T to 2 T, the quenching rate was decreased by (11.8 +/- 1.2)% and the yield of the escaped cation radical was increased by (90 +/- 8)%. (C) 1998 Elsevier Science B.V.

引用

页码：446 / 451

页数：6

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