Synthesis, conformational analysis, and binding properties of molecular clips with two different side walls

被引：46

作者：

Reek, JNH ^{[1
]}

Elemans, JAAW ^{[1
]}

Nolte, RJM ^{[1
]}

机构：

[1] CATHOLIC UNIV NIJMEGEN, DEPT ORGAN CHEM, NSR CTR, NL-6525 ED NIJMEGEN, NETHERLANDS

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1997年 / 62卷 / 07期

关键词：

SELECTIVE OXIDATION; PORPHYRIN; CATALYSIS; COMPLEXATION; SITES; DIHYDROXYBENZENES; CYCLOPHANES; CHEMISTRY; TWEEZERS; MODEL;

D O I：

10.1021/jo961382n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new general route toward the synthesis of diphenylglycoluril clips with two different side walls starting from the new precursor 6b and the known compound 2b is described. a variety of clips are accessible in this way, some of them containing metal binding ligand systems, viz. phenanthroline, pyridine, salophen, and porphyrin for future applications as supramolecular catalysts. The physical and binding properties of the new clips are presented and discussed.

引用

页码：2234 / 2243

页数：10

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