Tuning reaction rates by lateral strain in a palladium monolayer

被引：481

作者：

Kibler, LA ^{[1
]}

El-Aziz, AM

Hoyer, R

Kolb, DM

机构：

[1] Univ Ulm, Abt Elektrochem, D-89069 Ulm, Germany

[2] Natl Res Ctr, Dept Chem Phys, Dokki, Cairo, Egypt

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 14期

关键词：

adsorption; electrochemistry; heterogeneous catalysis; monolayers; oxidation; surface chemistry;

D O I：

10.1002/anie.200462127

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stretching exercises: The electrochemical behavior of pseudomorphic palladium monolayers (PdML) on various single-crystal electrodes is investigated (see picture) to demonstrate the influence of lateral compression and dilation on surface activity. The adsorption behavior and the catalytic activity for formic acid electrooxidation varies dramatically depending on whether the palladium monolayer is compressed or dilated by the single-crystal electrode. (Graph Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2080 / 2084

页数：5

共 42 条

[11] Effect of substrate strain on adsorption
Gsell, M
Jakob, P
Menzel, D
[J]. SCIENCE, 1998, 280 (5364) : 717 - 720
[12] Electronic factors determining the reactivity of metal surfaces
Hammer, B
Norskov, JK
[J]. SURFACE SCIENCE, 1995, 343 (03) : 211 - 220
[13] Voltammograms of the single-crystal electrodes of palladium in aqueous sulfuric acid electrolyte:: Pd(S)-[n(111) x (111)] and Pd(S)-[n(100) x (111)]
Hoshi, N
Kagaya, K
Hori, Y
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2000, 485 (01): : 55 - 60
[14] Electrochemical Pd deposition onto Rh(111): from cluster to monolayer growth
Hoyer, R
Kibler, LA
Kolb, DM
[J]. SURFACE SCIENCE, 2004, 562 (1-3) : 275 - 283
[15] The initial stages of palladium deposition onto Pt(111)
Hoyer, R
Kibler, LA
Kolb, DM
[J]. ELECTROCHIMICA ACTA, 2003, 49 (01) : 63 - 72
[16] ELECTRODEPOSITION PROCESSES OF PALLADIUM AND RHODIUM MONOLAYERS ON PT(111) AND PT(100) ELECTRODES STUDIED BY IR REFLECTION-ABSORPTION SPECTROSCOPY
INUKAI, J
ITO, M
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 358 (1-2): : 307 - 315
[17] CORRELATION BETWEEN SURFACE STRESS AND THE VIBRATIONAL SHIFT OF CO CHEMISORBED ON CU SURFACES
KAMPSHOFF, E
HAHN, E
KERN, K
[J]. PHYSICAL REVIEW LETTERS, 1994, 73 (05) : 704 - 707
[18] Kibler L. A., UNPUB
[19] Initial stages of Pd deposition on Au(hkl) - Part I: Pd on Au(111)
Kibler, LA
Kleinert, M
Randler, R
Kolb, DM
[J]. SURFACE SCIENCE, 1999, 443 (1-2) : 19 - 30
[20] Physical electrochemistry: Recent developments
Kibler, LA
Kolb, DM
[J]. ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2003, 217 (10): : 1265 - 1279

← 1 2 3 4 5 →