Thermal stability evaluation of PA6/LLDPE/SEBS-g-DEM blends

被引:10
作者
Catano, Luis
Albano, Carmen
Karam, Arquimedes
Perera, Rosestela
Silva, Pedro
机构
[1] Inst Venezolano Invest Cient, Ctr Quim, Lab Polimeros, Altos De Pipe, Venezuela
[2] Cent Univ Venezuela, Fac Ingn, Escuela Ingn Quim, Caracas, Venezuela
[3] Univ Simon Bolivar, Dept Mecan, Caracas, Venezuela
[4] Inst Venezolano Invest Cient, Lab Fis Mat Condensada, Ctr Fis, Altos De Pipe, Venezuela
关键词
activation energy; compatibility; IKP; polyethylene (PE);
D O I
10.1002/masy.200751114
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The thermal stability of a polyamide-6/low linear density polyethylene blend (PA6/LLDPE) was studied using thermal analysis techniques. The thermogravimetric studies carried out showed that when a diethyl maleate grafted styrene-ethylene/butadiene-styrene terpolymer (SEBS-g-DEM) is added to the PA6/LLDPE blend there is an actual enhancement of the thermal stability due to the increase in the interfacial area within the blend. The Invariant Kinetic Parameter method (IKP) proved to be a qualitative technique unfolding the type of degradation mechanisms taking place in the material vicinity. Nucleation and phase boundary reactions are the kinetic models of thermal decomposition with the most significant probability of occurring.
引用
收藏
页码:147 / 157
页数:11
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