学术探索
学术期刊
新闻热点
数据分析
智能评审

1,2-dimetalated benzene derivatives (1,2-C6H4MCH3)n of group 13 (M = Al, Ga, In)

被引：13
作者：
Dam, MA
Nijbacker, T
de Kanter, FJJ
Akkerman, OS
Bickelhaupt, F
Spek, AL
机构：
[1] Free Univ Amsterdam, Scheikundig Lab, NL-1081 HV Amsterdam, Netherlands
[2] Univ Utrecht, Bijvoet Ctr Biomol Res, NL-3584 CH Utrecht, Netherlands
来源：
ORGANOMETALLICS | 1999年 / 18卷 / 09期
关键词：
D O I：
10.1021/om9809217
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of (o-phenylene)magnesium (1) with CH3MCl2 (2; M = Al, Ga, In) gave access to the corresponding methyl(o-phenylene)metal compounds 3 ((1,2-C6H4MCH3)(n)). These novel 1,2-dimetalated benzene derivatives of group 13 were characterized by their spectral data and, in the case of 3b (M = Ga, n = 2), by a single-crystal X-ray structure determination.
引用
收藏
页码：1706 / 1709
页数：4
相关论文
共 44 条
  • [1] AFANASOVA OB, 1988, J GEN CHEM USSR, V58, P1499
  • [2] AFANASOVA OB, 1988, ZH OBSHCH KHIM, V58, P4119
  • [3] SYNTHESIS, CHARACTERIZATION, AND CRYSTAL AND MOLECULAR-STRUCTURE OF TRIMESITYLGALLIUM(III)
    BEACHLEY, OT
    CHURCHILL, MR
    PAZIK, JC
    ZILLER, JW
    [J]. ORGANOMETALLICS, 1986, 5 (09) : 1814 - 1817
  • [4] ELECTRON-DIFFRACTION STUDY OF MOLECULAR-STRUCTURE OF TRIMETHYLGALLIUM
    BEAGLEY, B
    SCHMIDLING, DG
    STEER, IA
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 1974, 21 (03) : 437 - 444
  • [5] BERUSKENS PT, 1996, DIRDIF SYSTEM
  • [6] BUDZELAAR PHM, 1992, IVORYSOFT
  • [7] 9,10-Dimetallatriptycenes of Group 14: A novel synthetic approach from ortho-phenylenemagnesium
    Dam, MA
    Akkerman, OS
    deKanter, FJJ
    Bickelhaupt, F
    Veldman, N
    Spek, AL
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (09) : 1139 - 1142
  • [8] Synthesis of alkynyl-substituted 9,10-dimetallatriptycenes of group 14 and their application in the preparation of a novel class of organometallic oligomers
    Dam, MA
    Hoogervorst, WJ
    de Kanter, FJJ
    Bickelhaupt, F
    Spek, AL
    [J]. ORGANOMETALLICS, 1998, 17 (09) : 1762 - 1768
  • [9] 9,10-dimetallatriptycenes of group 14: a structural study
    Dam, MA
    de Kanter, FJJ
    Bickelhaupt, F
    Smeets, WJJ
    Spek, AL
    Fornies-Camer, J
    Cardin, C
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 550 (1-2) : 347 - 353
  • [10] Synthesis, structure, and properties of an intramolecularly coordinated diindacycle: 9,10-dihydro-9,10-bis[2,6-bis((dimethylamino)methyl)phenyl]-9,10-diindaanthracene
    Dam, MA
    Nijbacker, T
    dePater, BC
    deKanter, FJJ
    Akkerman, OS
    Bickelhaupt, F
    Smeets, WJJ
    Spek, AL
    [J]. ORGANOMETALLICS, 1997, 16 (04) : 511 - 512
12345