Room temperature waterborne ATRP of n-butyl methacrylate in homogeneous alcoholic media

被引:48
作者
McDonald, S [1 ]
Rannard, SP [1 ]
机构
[1] Unilever Res Port Sunlight, Wirral CH63 3JW, Merseyside, England
关键词
D O I
10.1021/ma0115186
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A highly robust polymerization technique for the controlled synthesis of poly(n-butyl methacrylate) with no need to purify reagents is introduced. This synthesis is believed to be the first report of a room temperature "living" polymerization of a hydrophobic monomer under homogeneous waterborne conditions.
引用
收藏
页码:8600 / 8602
页数:3
相关论文
共 22 条
[1]   First example of the atom transfer radical polymerisation of an acidic monomer: direct synthesis of methacrylic acid copolymers in aqueous media [J].
Ashford, EJ ;
Naldi, V ;
O'Dell, R ;
Billingham, NC ;
Armes, SP .
CHEMICAL COMMUNICATIONS, 1999, (14) :1285-1286
[2]   Copper(I) mediated living radical polymerisation in an ionic liquid [J].
Carmichael, AJ ;
Haddleton, DM ;
Bon, SAF ;
Seddon, KR .
CHEMICAL COMMUNICATIONS, 2000, (14) :1237-1238
[3]   Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process [J].
Chiefari, J ;
Chong, YK ;
Ercole, F ;
Krstina, J ;
Jeffery, J ;
Le, TPT ;
Mayadunne, RTA ;
Meijs, GF ;
Moad, CL ;
Moad, G ;
Rizzardo, E ;
Thang, SH .
MACROMOLECULES, 1998, 31 (16) :5559-5562
[4]  
Coca S, 1998, J POLYM SCI POL CHEM, V36, P1417, DOI 10.1002/(SICI)1099-0518(19980715)36:9<1417::AID-POLA9>3.0.CO
[5]  
2-P
[6]  
FURLONG S, 2000, POLYM PREPR, V41, P450
[7]   Controlled/"living" radical polymerization applied to water-borne systems [J].
Gaynor, SG ;
Qiu, J ;
Matyjaszewski, K .
MACROMOLECULES, 1998, 31 (17) :5951-5954
[8]   NARROW MOLECULAR-WEIGHT RESINS BY A FREE-RADICAL POLYMERIZATION PROCESS [J].
GEORGES, MK ;
VEREGIN, RPN ;
KAZMAIER, PM ;
HAMER, GK .
MACROMOLECULES, 1993, 26 (11) :2987-2988
[9]   Copper(I)-mediated living radical polymerization under fluorous biphasic conditions [J].
Haddleton, DM ;
Jackson, SG ;
Bon, SAF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (07) :1542-1543
[10]   LIVING POLYMERIZATIONS OF ACRYLIC-MONOMERS WITH ALUMINIOPORPHYRIN [J].
INOUE, S ;
AIDA, T ;
KUROKI, M ;
HOSOKAWA, Y .
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1990, 32 :255-265