Ceric ammonium nitrate (CAN) mediated novel dimerizations of 4-hydroxyquinolin-2(1H)-ones:: the first example of reactions of oxygen-centered radicals from 1,3-dicarbonyl compounds

被引：22

作者：

Ye, JH ^{[1
]}

Xue, J ^{[1
]}

Ling, KQ ^{[1
]}

Xu, JH ^{[1
]}

机构：

[1] Nanjing Univ, Dept Chem, Nanjing 210093, Peoples R China

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 07期

关键词：

D O I：

10.1016/S0040-4039(98)02644-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of 4-hydroxyquinolin-2(1H)-ones (1) and 3-alkylated 4-hydroxyquinolin-2(1H)ones (2) with CAN in methanol gave quinolin-2(1H)-one dimers 3, 10 and 11 with C-C and C-O linkages between the two nitrogen containing sis-member rings, respectively, showing the ambident reactivities of alpha,alpha'-dicarbonylalkyl radicals as carbon- and oxygen-centered radicals. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1365 / 1368

页数：4

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