Electropolymerization of [Ru(bpy)(CO)2Cl2] (bpy=2,2′-bipyridine:: a revisited trans versus cis(Cl) isomeric influence study

被引：36

作者：

Chardon-Noblat, S

Da Costa, P

Deronzier, A

Haukka, M

Pakkanen, TA

Ziessel, R

机构：

[1] Univ Grenoble 1, CNRS, UMR 5630, Lab Electrochim Organ & Photochim Redox, F-38041 Grenoble 9, France

[2] Univ Joensuu, Dept Chem, FIN-80101 Joensuu, Finland

[3] EPCMULP, ESA 7008, Lab Chim Elect & Photon Mol, F-67087 Strasbourg 2, France

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2000年 / 490卷 / 1-2期

关键词：

ruthenium complexes; stereochemistry; organometallic dimers and polymers; electrocatalysis;

D O I：

10.1016/S0022-0728(00)00228-X

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The mono-bipyridine bis carbonyl complex [Ru(bpy)(CO)(2)Cl-2] exists in two stereoisomeric forms having a trans(Cl)/cis(CO) (1) and cis(Cl)/cis(CO) (2) configuration. In previous work we reported that only the trans(Cl)/cis(CO) isomer 1 leads by a two-electron reduction to the formation of [Ru(bpy)(CO)(2)](n) polymeric film on an electrode surface. This initial statement was overstated, as both isomers allowed the build up of polymers. A detailed comparison of the electropolymerization of both isomers is reported here, as well as the reduction into dimers of parent stereoisomer [Ru(bpy)(CO)(2)(C(O)OMe)Cl] complexes 3 and 4 obtained as side products during the synthesis of 1 and 2. (C) 2000 Published by Elsevier Science S.A.

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页码：62 / 69

页数：8

相关论文

共 17 条

[1] RUTHENIUM CARBONYL-COMPLEXES .1. SYNTHESIS OF [RU(CO)2(BIDENTATE)2]2+ COMPLEXES [J].

BLACK, DS ;

DEACON, GB ;

THOMAS, NC .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1982, 35 (12) :2445-2453

[2] Electrochemical formation and spectroelectrochemical characterization of organometallic [Ru(L)(CO)2]n polymers;: L = disubstituted-2,2′-bipyridine [J].

Caix-Cecillon, C ;

Chardon-Noblat, S ;

Deronzier, A ;

Haukka, M ;

Pakkanen, TA ;

Ziessel, R ;

Zsoldos, D .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 466 (02) :187-196

[3] Electroreduction of CO, catalyzed by polymeric [Ru(bpy)(CO)2]n films in aqueous media:: parameters influencing the reaction selectivity [J].

Chardon-Noblat, S ;

Deronzier, A ;

Ziessel, R ;

Zsoldos, D .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1998, 444 (02) :253-260

[4] Selective synthesis and electrochemical behavior of trans(Cl)- and cis(Cl)-[Ru(bpy)(CO)(2)Cl-2] complexes (bpy = 2,2'-bipyridine). Comparative studies of their electrocatalytic activity toward the reduction of carbon dioxide [J].

ChardonNoblat, S ;

Deronzier, A ;

Ziessel, R ;

Zsoldos, D .

INORGANIC CHEMISTRY, 1997, 36 (23) :5384-5389

[5] Mode of formaiton of polymeric [{Ru(bipy)(CO)(2)}(n)] (bipy=2,2'-bipyridine) films [J].

ChardonNoblat, S ;

Deronzier, A ;

Zsoldos, D ;

Ziessel, R ;

Haukka, M ;

Pakkanen, T ;

Venalainen, T .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (12) :2581-2583

[6] ELECTROCATALYTIC REDUCTION OF CARBON-DIOXIDE WITH MONO(BIPYRIDINE)CARBONYLRUTHENIUM COMPLEXES IN SOLUTION OR AS POLYMERIC THIN-FILMS [J].

COLLOMBDUNANDSAUTHIER, MN ;

DERONZIER, A ;

ZIESSEL, R .

INORGANIC CHEMISTRY, 1994, 33 (13) :2961-2967

[7] ELECTROCHEMICAL-BEHAVIOR OF [RU(II)(L)(CO)2CL2], [RU(II)(L)(CO)CL3][ME4N] AND [RU(II)(L)(CO)2(CH3CN)2][CF3SO3]2 COMPLEXES (L=2,2'-BIPYRIDINE OR 4,4'-ISOPROPOXYCARBONYL-2,2'-BIPYRIDINE) [J].

COLLOMBDUNANDSAUTHIER, MN ;

DERONZIER, A ;

ZIESSEL, R .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 350 (1-2) :43-55

[8] ELECTROCATALYTIC REDUCTION OF CO2 IN WATER ON A POLYMERIC [(RU-0(BPY)(CO)(2))(N)] (BPY=2,2'-BIPYRIDINE) COMPLEX IMMOBILIZED ON CARBON ELECTRODES [J].

COLLOMBDUNANDSAUTHIER, MN ;

DERONZIER, A ;

ZIESSEL, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (02) :189-191

[9] ELECTROCHEMICAL ELABORATION OF THIN-FILMS OF POLY[RUII(L)(CO)2CL2] (L = 4-(2-PYRROL-1-YLETHYL)-4'-METHYL-2,2'-BIPYRIDINE OR 4,4'-BIS((3-PYRROL-1-YLPROPYLOXY)CARBONYL)-2,2'-BIPYRIDINE) - PHOTOCHEMICAL PROPERTIES AND PHOTOIMAGING [J].

COLLOMBDUNANDSAUTHIER, MN ;

DERONZIER, A ;

ZIESSEL, R .

JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (22) :5973-5979

[10] Light-induced decarbonylation, solvolysis, and isomerization of Ru(L)(CO)2Cl2 (L=2,2′-bipyridine and 4,4′-dimethyl-2,2′-bipyridine) in acetonitrile [J].

Eskelinen, E ;

Haukka, M ;

Venäläinen, T ;

Pakkanen, TA ;

Wasberg, M ;

Chardon-Noblat, S ;

Deronzier, A .

ORGANOMETALLICS, 2000, 19 (02) :163-169