Anion selective recognition and optical/electrochemical sensing by novel transition-metal receptor systems

被引：342

作者：

Beer, PD

机构：

[1] Inorganic Chemistry Laboratory, University of Oxford, Oxford, OX1 3QR, South Parks Road

[2] Université Louis Pasteur, Strasbourg

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 06期

关键词：

D O I：

10.1039/cc9960000689

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Appropriately designed charged or neutral redox- and/or photo-active transition-metal organometallic and coordination receptor systems can selectively recognise and sense anionic guest species by electrochemical and/or optical methodologies, The topological positioning of the transition-metal Lewis-acid centres and of the ubiquitous hydrogen-bonding functionalities, such as amide (CO-NH) groups, dictates the anion selectivity trend and sensing proficiency the particular receptor displays.

引用

页码：689 / 696

页数：8

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