共 12 条
Macrocycles from simple building blocks by a multifold Heck-type coupling reaction
被引:17
作者:
Dyker, G
Kadzimirsz, D
Henkel, G
机构:
[1] Ruhr Univ Bochum, Fak Chem, D-44780 Bochum, Germany
[2] Univ Gesamthsch Paderborn, Fachbereich Chem & Chemietech 13, D-33098 Paderborn, Germany
关键词:
domino processes;
Heck reaction;
ketones;
macrocycles;
palladium catalysis;
D O I:
10.1016/j.tetlet.2003.09.009
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
Diiodobenzenes and bisallylic alcohols-two equivalents of each-were coupled under palladium catalysis to give oxofunctionalized macrocycles as 2:2 products. The 1:1 products as medium sized rings were disfavoured and not observed. (C) 2003 Elsevier Ltd. All rights reserved.
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页码:7905 / 7907
页数:3
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