Synthesis of (-)-erythrodiene via intramolecular Pd-catalyzed Zn-ene reaction

被引：18

作者：

Oppolzer, W ^{[1
]}

Flachsmann, F ^{[1
]}

机构：

[1] Univ Geneva, Dept Chim Organ, CH-1211 Geneva 4, Switzerland

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 28期

关键词：

spiro compounds; ene reactions; transmetalation; diastereoselection;

D O I：

10.1016/S0040-4039(98)00991-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly diastereoselective synthesis of (-)-Erythrodiene was achieved via an intramolecular Pd-catalyzed Znene reaction as the key step. It was found that Pd(OAc)(2)/Bu3P was a superior catalyst for this reaction to Pd(PPh3)(4). (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：5019 / 5022

页数：4

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