Facile synthesis and catalytic activity of MoS2/TiO2 by a photodeposition-based technique and its oxidized derivative MoO3/TiO2 with a unique photochromism

被引：94

作者：

Kanda, Shigeki ^{[1
]}

Akita, Tomoki ^{[2
]}

Fujishima, Musashi ^{[1
]}

Tada, Hiroaki ^{[1
]}

机构：

[1] Kinki Univ, Dept Appl Chem, Sch Sci & Engn, Osaka 5778502, Japan

[2] Natl Inst Adv Ind Sci & Technol, Osaka 5638577, Japan

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2011年 / 354卷 / 02期

关键词：

Single precursor photodeposition; Photocatalysis; Photochromism; Metal oxide; Metal chalcogenide; SIZE; MOS2; SEMICONDUCTOR; NANOPARTICLE; CDS;

D O I：

10.1016/j.jcis.2010.11.007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

UV-light irradiation to TiO2 in an aqueous ethanol solution of (NH4)(2)MoS4 under deaerated conditions has yielded molybdenum(IV) sulfide nanoparticles on a TiO2 surface (MoS2/TiO2) to be transformed into molybdenum(VI) oxide species highly dispersed at a molecular level by a subsequent heating at 773 K in air (m-MoO3/TiO2). In HCOOH aqueous solutions, the MoS2/TiO2 system exhibits a high level of photocatalytic activity for H-2 generation, while the m-MoO3/TiO2 system shows unique photochromism. (C) 2010 Elsevier Inc. All rights reserved.

引用

页码：607 / 610

页数：4

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