Towards an environmentally-friendly laboratory: dimensionality and reactivity in the mechanosynthesis of metal-organic compounds

被引：83

作者：

Strukil, Vjekoslav ^{[1
]}

Fabian, Laszlo ^{[2
]}

Reid, David G. ^{[3
]}

Duer, Melinda J. ^{[3
]}

Jackson, Graham J. ^{[4
]}

Eckert-Maksic, Mirjana ^{[1
]}

Friscic, Tomislav ^{[3
]}

机构：

[1] Rudjer Boskovic Inst, Div Organ Chem & Biochem, Lab Phys Organ Chem, Zagreb 10002, Croatia

[2] Univ Coll Cork, Dept Chem, Cork, Ireland

[3] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[4] Univ Cape Town, Dept Chem, ZA-7700 Rondebosch, South Africa

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 48期

基金：

英国生物技术与生命科学研究理事会;

关键词：

X-RAY-DIFFRACTION; QUANTITATIVE MECHANOCHEMICAL PREPARATION; COORDINATION POLYMERS; SOLVENT; 1D; CONSTRUCTION; MECHANISM;

D O I：

10.1039/c0cc03822a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present a proof-of-principle study of an environmentally-friendly approach to laboratory research, in which the synthesis and structural characterisation of metal-organic complexes and frameworks are achieved without using bulk solvents; our study addresses the use of heteroditopic ligands for manipulating the dimensionality of metal-organic materials and describes how kinetic obstacles in such mechanosynthesis can be overcome.

引用

页码：9191 / 9193

页数：3

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