Preparation of nickel(0) nanoparticles by arene-catalysed reduction of different nickel chloride-containing systems

被引:28
作者
Alonso, F.
Calvino, J. J.
Osante, I.
Yus, M.
机构
[1] Univ Alicante, Fac Ciencias, Dept Quim Organ, Alicante 03080, Spain
[2] Univ Alicante, ISO, Alicante 03080, Spain
[3] Fac Ciencias, Dept Ciencia Mat & Ingn Met & Quim Inorgan, Cadiz 11510, Spain
关键词
nickel; nanoparticles; reduction;
D O I
10.1080/17458080601027652
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nickel(0) nanoparticles with diameters < 6 nm have been prepared in a straightforward manner by reduction of different nickel(II) chloride-containing systems with lithium powder and a catalytic amount of an arene in THF at room temperature. The properties and reactivity of the different nickel nanoparticles have been studied and compared.
引用
收藏
页码:419 / 433
页数:15
相关论文
共 41 条
[1]   Highly stereoselective semihydrogenation of alkynes promoted by nickel(0) nanoparticles [J].
Alonso, F ;
Osante, M ;
Yus, M .
ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (03) :305-308
[2]   A new straightforward and mild preparation of nickel(0) nanoparticles [J].
Alonso, F ;
Calvino, JJ ;
Osante, I ;
Yus, M .
CHEMISTRY LETTERS, 2005, 34 (09) :1262-1263
[3]   The NiCl2-Li-arene(cat.) combination: A versatile reducing mixture [J].
Alonso, F ;
Yus, M .
CHEMICAL SOCIETY REVIEWS, 2004, 33 (05) :284-293
[4]   The NiCl2-Li-arene (cat.) combination as reducing system, part 9:: Catalytic hydrogenation of organic compounds using the NiCl2-Li-(Naphthalene or polymer-supported naphthalene) (cat.) combination [J].
Alonso, F ;
Candela, P ;
Gómez, C ;
Yus, M .
ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (1-2) :275-279
[5]  
Alonso F, 2001, ADV SYNTH CATAL, V343, P188, DOI 10.1002/1615-4169(20010226)343:2<188::AID-ADSC188>3.0.CO
[6]  
2-8
[7]   Hydrogenation of olefins with hydrated nickel chloride, lithium and a catalytic amount of naphthalene [J].
Alonso, F ;
Yus, M .
TETRAHEDRON LETTERS, 1996, 37 (38) :6925-6928
[8]  
ALONSO F, 2006, IN PRESS TETRAHEDRON
[9]  
ALONSO F, 2006, IN PRESS SYNLETT
[10]  
ALONSO F, 2006, CHEM SOC REV, V348, P305