Spectroscopy and dynamics of the H2-CN van der Waals complex

被引：27

作者：

Chen, YL ^{[1
]}

Heaven, MC ^{[1
]}

机构：

[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1998年 / 109卷 / 13期

关键词：

D O I：

10.1063/1.477132

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Spectra for the H-2-CN and D-2-CN complexes have been observed in association with the monomer B (2)Sigma(+)-X(2)Sigma(+) and A (2)Pi-X(2)Sigma(+) transitions. Ground state dissociation energies of D-0" = 38+/-1 cm(-1) (H-2-CN) and D-0" = 42+/-1 cm(-1) (D-2-CN) were determined. Electronically nonadiabatic predissociations of H-2/D-2-CN(A) complexes were characterized using double resonance techniques. (C) 1998 American Institute of Physics. [S0021-9606(98)03437-0].

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页码：5171 / 5174

页数：4

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