Cluster-eliminating filter for depositing cluster-free a-Si:H films by plasma chemical vapor deposition -: art. no. 113501

被引:17
作者
Koga, K [1 ]
Kaguchi, N [1 ]
Bando, K [1 ]
Shiratani, M [1 ]
Watanabe, Y [1 ]
机构
[1] Kyushu Univ, Dept Elect, Fukuoka 8128581, Japan
基金
日本学术振兴会;
关键词
D O I
10.1063/1.2126572
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
A cluster-eliminating filter is developed to reduce a volume fraction V-F of amorphous silicon nanoparticles above approximately 1 nm in size (referred to as a cluster) incorporated into a-Si:H films. The filter reduces the V-F value by using the difference between a sticking probability of clusters and a surface reaction probability of SiH3 radicals, which are the predominant deposition radicals. By employing the filter together with a cluster-suppressed plasma chemical vapor deposition reactor, the V-F value is reduced below 1/180 compared to that for the conventional device quality films. Such cluster-free a-Si:H films have an extremely small hydrogen concentration associated with Si-H-2 bonds below 5.46x10(-3) at. %. (c) 2005 American Institute of Physics.
引用
收藏
页码:1 / 4
页数:4
相关论文
共 17 条
[1]  
BRODSKY MH, 1977, PHYS REV B, V16, P3556, DOI 10.1103/PhysRevB.16.3556
[2]   RESISTANCE OF A GASEOUS MEDIUM TO MOTION OF A SPHERICAL PARTICLE OF A SIZE COMPARABLE TO MEAN FREE PATH OF GAS MOLECULES [J].
FUCHS, NA ;
STECHKINA, IB .
TRANSACTIONS OF THE FARADAY SOCIETY, 1962, 58 (478) :1949-+
[3]  
HINDS WC, 1982, AEROSOL TECHNOLOGY, P138
[4]   In situ observation of nucleation and subsequent growth of clusters in silane radio frequency discharges [J].
Koga, K ;
Matsuoka, Y ;
Tanaka, K ;
Shiratani, M ;
Watanabe, Y .
APPLIED PHYSICS LETTERS, 2000, 77 (02) :196-198
[5]   Correlation between volume fraction of clusters incorporated into a-Si:H films and hydrogen content associated with Si-H2 bonds in the films [J].
Koga, K ;
Kaguchi, N ;
Shiratani, M ;
Watanabe, Y .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2004, 22 (04) :1536-1539
[6]   Cluster-suppressed plasma chemical vapor deposition method for high quality hydrogenated amorphous silicon films [J].
Koga, K ;
Kai, M ;
Shiratani, M ;
Watanabe, Y ;
Shikatani, N .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 2002, 41 (2B) :L168-L170
[7]  
KOGA K, UNPUB
[8]   SURFACE MOBILITY OF C-60 ON SIO2 [J].
MOALEM, M ;
BALOOCH, M ;
HAMZA, AV ;
SIEKHAUS, WJ ;
OLANDER, DR .
JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (06) :4855-4859
[9]   Amorphous silicon solar cells deposited at high growth rate [J].
Nishimoto, T ;
Takai, M ;
Miyahara, H ;
Kondo, M ;
Matsuda, A .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2002, 299 :1116-1122
[10]   Surface reaction probabilities and kinetics of H, SiH3, Si2H5, CH3, and C2H5 during deposition of a-Si:H and a-C:H from H2, SiH4, and CH2 discharges [J].
Perrin, J ;
Shiratani, M ;
Kae-Nune, P ;
Videlot, H ;
Jolly, J ;
Guillon, J .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1998, 16 (01) :278-289