N-Heterocyclic carbene adducts of orthopalladated triarylphosphite complexes

被引：56

作者：

Bedford, RB

Betham, M

Blake, ME

Frost, RM

Horton, PN

Hursthouse, MB

López-Nicolás, RM

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[2] Univ Exeter, Dept Chem, Exeter EX4 4QD, Devon, England

[3] Univ Southampton, Dept Chem, EPSRC Natl Crystallog Serv, Southampton SO17 1BJ, Hants, England

[4] Univ Murcia, Fac Quim, Dept Quim Inorgan, Grp Quim Organomet, E-30071 Murcia, Spain

来源：

DALTON TRANSACTIONS | 2005年 / 16期

关键词：

D O I：

10.1039/b506286a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Carbene adducts of orthopalladated triarylphosphite complexes have been synthesised and characterised. The structures of three of these complexes were determined by single-crystal X-ray analysis. The complexes are active in the Suzuki coupling of a range of aryl bromide substrates.

引用

页码：2774 / 2779

页数：6

共 28 条

[11] Observations on the intramolecular Heck reactions of aromatic chlorides using palladium/imidazolium salts
Caddick, S
Kofie, W
[J]. TETRAHEDRON LETTERS, 2002, 43 (51) : 9347 - 9350
[12] Collman J.P., 1987, PRINCIPLES APPL ORGA
[13] TRANSFORMATIONS OF CHLOROARENES, CATALYZED BY TRANSITION-METAL COMPLEXES
GRUSHIN, VV
ALPER, H
[J]. CHEMICAL REVIEWS, 1994, 94 (04) : 1047 - 1062
[14] Heck R.F., 1985, PALLADIUM REAGENTS O
[15] Hooft R., 1998, COLLECT DATA COLLECT
[16] Synthetic, structural, and mechanistic studies on the oxidative addition of aromatic chlorides to a palladium (N-heterocyclic carbene) complex:: Relevance to catalytic amination
Lewis, AKD
Caddick, S
Cloke, FGN
Billingham, NC
Hitchcock, PB
Leonard, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (33) : 10066 - 10073
[17] Littke AF, 2002, ANGEW CHEM INT EDIT, V41, P4176, DOI 10.1002/1521-3773(20021115)41:22<4176::AID-ANIE4176>3.0.CO
[18] 2-U
[19] A general and versatile approach to thermally generated N-heterocyclic carbenes
Nyce, GW
Csihony, S
Waymouth, RM
Hedrick, JL
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (16) : 4073 - 4079
[20] Processing of X-ray diffraction data collected in oscillation mode
Otwinowski, Z
Minor, W
[J]. MACROMOLECULAR CRYSTALLOGRAPHY, PT A, 1997, 276 : 307 - 326

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