Generation and characterization of the tris(pentafluorophenyl)borane radical anion

被引：68

作者：

Kwaan, RJ ^{[1
]}

Harlan, CJ ^{[1
]}

Norton, JR ^{[1
]}

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 17期

关键词：

D O I：

10.1021/om010272q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The anion derived from B(C6F5)(3) has been detected by EPR, and the boron and fluorine hyperfine splitting constants have been determined. Treatment of B(C6F5)(3) with the reductant Cp*Co-2 in THF at -50 degreesC rapidly results in a dark blue (lambda (max) = 603 nm) paramagnetic solution containing the anion radical. The half-life for disappearance of lambda (max), about 10 min at room temperature, is consistent with that of the EPR signal.

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页码：3818 / 3820

页数：3

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