Transition metal complexes for photovoltaic and light emitting applications

被引:150
作者
Nazeeruddin, M. K. [1 ]
Graetzel, M. [1 ]
机构
[1] Swiss Fed Inst Technol, Sch Basic Life Sci, Inst Mol & Biol Chem, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland
来源
PHOTOFUNCTIONAL TRANSITION METALS COMPLEXES | 2007年 / 123卷
关键词
dye-sensitized solar cells; iridium triplet emitters; light emitting electrochemical cells; OLED; photovoltaic; ruthenium sensitizers;
D O I
10.1007/430_2007_056
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The aim of this chapter is to give an in-depth analysis of transition metal complexes that are useful in conversion of solar energy into electricity, and in organic light emitting diodes. In the first part we discuss the historical background of sensitization phenomenon, operating principles of dye-sensitized solar cells, tuning of photophysical and electrochemical properties of sensitizers, evolution of photovoltaic performance, present status and future prospects for dye-sensitized solar cells. In the second part, we elucidate the modulation of phosphorescent color and quantum yields in neutral, cationic, and anionic iridium complexes and their application in light emitting devices.
引用
收藏
页码:113 / 175
页数:63
相关论文
共 131 条
[1]   Nearly 100% internal phosphorescence efficiency in an organic light-emitting device [J].
Adachi, C ;
Baldo, MA ;
Thompson, ME ;
Forrest, SR .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (10) :5048-5051
[2]   High-efficiency organic electrophosphorescent devices with tris(2-phenylpyridine)iridium doped into electron-transporting materials [J].
Adachi, C ;
Baldo, MA ;
Forrest, SR ;
Thompson, ME .
APPLIED PHYSICS LETTERS, 2000, 77 (06) :904-906
[3]   BLACK MLCT ABSORBERS [J].
ANDERSON, PA ;
STROUSE, GF ;
TREADWAY, JA ;
KEENE, FR ;
MEYER, TJ .
INORGANIC CHEMISTRY, 1994, 33 (18) :3863-3864
[4]   CHEMICAL MODIFICATION OF A TITANIUM(IV) OXIDE ELECTRODE TO GIVE STABLE DYE SENSITIZATION WITHOUT A SUPERSENSITIZER [J].
ANDERSON, S ;
CONSTABLE, EC ;
DAREEDWARDS, MP ;
GOODENOUGH, JB ;
HAMNETT, A ;
SEDDON, KR ;
WRIGHT, RD .
NATURE, 1979, 280 (5723) :571-573
[5]   Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies [J].
Bach, U ;
Lupo, D ;
Comte, P ;
Moser, JE ;
Weissörtel, F ;
Salbeck, J ;
Spreitzer, H ;
Grätzel, M .
NATURE, 1998, 395 (6702) :583-585
[6]   Transient analysis of organic electrophosphorescence. II. Transient analysis of triplet-triplet annihilation [J].
Baldo, MA ;
Adachi, C ;
Forrest, SR .
PHYSICAL REVIEW B, 2000, 62 (16) :10967-10977
[7]   Very high-efficiency green organic light-emitting devices based on electrophosphorescence [J].
Baldo, MA ;
Lamansky, S ;
Burrows, PE ;
Thompson, ME ;
Forrest, SR .
APPLIED PHYSICS LETTERS, 1999, 75 (01) :4-6
[8]   Luminescent and redox-active polynuclear transition metal complexes [J].
Balzani, V ;
Juris, A ;
Venturi, M ;
Campagna, S ;
Serroni, S .
CHEMICAL REVIEWS, 1996, 96 (02) :759-833
[9]  
Barbe CJ, 1997, J AM CERAM SOC, V80, P3157, DOI 10.1111/j.1151-2916.1997.tb03245.x
[10]   Synthesis, characterization, and DFT-TDDFT computational study of a ruthenium complex containing a functionalized tetradentate ligand [J].
Barolo, C. ;
Nazeeruddin, Md. K. ;
Fantacci, Simona ;
Di Censo, D. ;
Comte, P. ;
Liska, P. ;
Viscardi, G. ;
Quagliotto, P. ;
De Angelis, Filippo ;
Ito, S. ;
Graetzel, M. .
INORGANIC CHEMISTRY, 2006, 45 (12) :4642-4653