Transition metal complexes for photovoltaic and light emitting applications

被引：150

作者：

Nazeeruddin, M. K. ^{[1
]}

Graetzel, M. ^{[1
]}

机构：

[1] Swiss Fed Inst Technol, Sch Basic Life Sci, Inst Mol & Biol Chem, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland

来源：

PHOTOFUNCTIONAL TRANSITION METALS COMPLEXES | 2007年 / 123卷

关键词：

dye-sensitized solar cells; iridium triplet emitters; light emitting electrochemical cells; OLED; photovoltaic; ruthenium sensitizers;

D O I：

10.1007/430_2007_056

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The aim of this chapter is to give an in-depth analysis of transition metal complexes that are useful in conversion of solar energy into electricity, and in organic light emitting diodes. In the first part we discuss the historical background of sensitization phenomenon, operating principles of dye-sensitized solar cells, tuning of photophysical and electrochemical properties of sensitizers, evolution of photovoltaic performance, present status and future prospects for dye-sensitized solar cells. In the second part, we elucidate the modulation of phosphorescent color and quantum yields in neutral, cationic, and anionic iridium complexes and their application in light emitting devices.

引用

页码：113 / 175

页数：63

共 131 条

[41] LIGHT-INDUCED REDOX REACTIONS IN NANOCRYSTALLINE SYSTEMS [J].

HAGFELDT, A ;

GRATZEL, M .

CHEMICAL REVIEWS, 1995, 95 (01) :49-68

[42] Solid-state light-emitting devices based on the tris-chelated ruthenium(II) complex. 2. Tris(bipyridyl)ruthenium(II) as a high-brightness emitter [J].

Handy, ES ;

Pal, AJ ;

Rubner, MF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (14) :3525-3528

[43] Dye-sensitized nanocrystalline TiO2 solar cells based on ruthenium(II) phenanthroline complex photosensitizers [J].

Hara, K ;

Sugihara, H ;

Tachibana, Y ;

Islam, A ;

Yanagida, M ;

Sayama, K ;

Arakawa, H ;

Fujihashi, G ;

Horiguchi, T ;

Kinoshita, T .

LANGMUIR, 2001, 17 (19) :5992-5999

[44] PHYSICS CONSIDERATIONS OF SOLAR-ENERGY CONVERSION [J].

HAUGHT, AF .

JOURNAL OF SOLAR ENERGY ENGINEERING-TRANSACTIONS OF THE ASME, 1984, 106 (01) :3-15

[45] Theoretical studies of the ground and excited electronic states in cyclometalated phenylpyridine Ir(III) complexes using density functional theory [J].

Hay, PJ .

JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (08) :1634-1641

[46]

HINSCH A, 2000, P 16 UER PV SOL EN C, V32

[47] New trends in the use of transition metal-ligand complexes for applications in electroluminescent devices [J].

Holder, E ;

Langeveld, BMW ;

Schubert, US .

ADVANCED MATERIALS, 2005, 17 (09) :1109-1121

[48] Electroluminescence from triplet excited states of benzophenone [J].

Hoshino, S ;

Suzuki, H .

APPLIED PHYSICS LETTERS, 1996, 69 (02) :224-226

[49] Iridium(III) complexes with orthometalated quinoxaline ligands: Subtle tuning of emission to the saturated red color [J].

Hwang, FM ;

Chen, HY ;

Chen, PS ;

Liu, CS ;

Chi, Y ;

Shu, CF ;

Wu, FL ;

Chou, PT ;

Peng, SM ;

Lee, GH .

INORGANIC CHEMISTRY, 2005, 44 (05) :1344-1353

[50] EXCITED-STATE ABSORPTION-SPECTROSCOPY OF ORTHO-METALATED IR(III) COMPLEXES [J].

ICHIMURA, K ;

KOBAYASHI, T ;

KING, KA ;

WATTS, RJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (24) :6104-6106

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