NMR detection of single-walled carbon nanotubes in solution

被引：56

作者：

Kitaygorodskiy, A

Wang, W

Xie, SY

Lin, Y

Fernando, KAS

Wang, X

Qu, LW

Chen, B

Sun, YP ^{[1
]}

机构：

[1] Clemson Univ, Dept Chem, Clemson, SC 29634 USA

[2] Clemson Univ, Lab Emerging Mat & Technol, Clemson, SC 29634 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 20期

关键词：

D O I：

10.1021/ja050342a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The detection of nanotube carbons in solution by C-13 NMR is reported. The highly soluble sample was from the functionalization of C-13-enriched single-walled carbon nanotubes (SWNTs) with diamineterminated oligomeric poly(ethylene glycol) (PEG(1500N)). The ferromagnetic impurities due to the residual metal catalysts were removed from the sample via repeated magnetic separation. The nanotube carbon signals are broad but partially resolved into two overlapping peaks, which are tentatively assigned to nanotube carbons on semiconducting (upfield) and metallic (downfield) SWNTs. The solid-state NMR signals of the same sample are similarly resolved. Mechanistic and practical implications of the results are discussed.

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页码：7517 / 7520

页数：4

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