Magnetic interactions in carbon nanostructures

被引:109
作者
Goze-Bac, C
Latil, S
Lauginie, P
Jourdain, V
Conard, J
Duclaux, L
Rubio, A
Bernier, P
机构
[1] Univ Montpellier 2, UMR 5581, GDPC, F-34095 Montpellier 5, France
[2] Univ Orleans, CNRS, CRMD, F-45071 Orleans, France
[3] Univ Valladolid, Dept Fis Teor, E-47011 Valladolid, Spain
关键词
carbon nanotubes; nuclear magnetic resonance; electron spin resonance; modeling; magnetic properties;
D O I
10.1016/S0008-6223(02)00061-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A review is given of local and non-local magnetic interactions in carbon nanotubes as observed by NMR and EPR. Since reference to graphite and graphene is compulsory, an extended review of the NMR and EPR of graphite and related materials, including GIC, is given. Then EPR, and either static or high-resolution NMR experimental results, both in pure and intercalated MWNT or SWNT, are then reviewed. From high-resolution C-13-NMR in association with a theoretical modelization, it is shown how conducting and semiconducting carbon nanotubes might be discriminated. The benefits of high-resolution NMR for the characterization of carbon nanotube functionalization are described. The strong interdependence of all carbon material studies is clearly highlighted throughout the paper. (C) 2002 Published by Elsevier Science Ltd.
引用
收藏
页码:1825 / 1842
页数:18
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