Ammonium formate/palladium on carbon: A versatile system for catalytic hydrogen transfer reductions of carbon-carbon double bonds

被引：48

作者：

Paryzek, Z ^{[1
]}

Koenig, H ^{[1
]}

Tabaczka, B ^{[1
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, Poznan, Poland

来源：

SYNTHESIS-STUTTGART | 2003年 / 13期

关键词：

catalytic transfer hydrogenations; reduction; ammonium formate; olefins; alpha; beta-unsaturated ketones;

D O I：

10.1055/s-2003-41024

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various carbon-carbon double bonds in olefins and alpha,beta-unsaturated ketones were effectively reduced to the corresponding alkanes and saturated ketones, using ammonium formate as a hydrogen transfer agent in the presence of Pd/C as catalyst in refluxing methanol.

引用

收藏

页码：2023 / 2026

页数：4

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