NHC-carbene cyclopentadienyl iron based catalyst for a general and efficient hydrosilylation of imines

被引：106

作者：

Castro, Luis C. Misal ^{[1
]}

Sortais, Jean-Baptiste ^{[1
]}

Darcel, Christophe ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS, UMR 6226, Team Catalysis & Organometall, F-35042 Rennes, France

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 01期

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; C BOND-CLEAVAGE; ENANTIOSELECTIVE HYDROSILYLATION; TRANSITION-METAL; KETONES; COMPLEXES; CONVENIENT; REDUCTION; CARBONYL; AMINES;

D O I：

10.1039/c1cc14403k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general and efficient hydrosilylation of imines catalysed by a well defined NHC-carbene cyclopentadienyl iron complex has been developed. Both aldimines and ketimines are converted to the corresponding amines under mild conditions, and under visible light activation.

引用

页码：151 / 153

页数：3

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