Phosphabicyclononane-containing Ru complexes: Efficient pre-catalysts for olefin metathesis reactions

被引：37

作者：

Boeda, Fabien ^{[1
]}

Clavier, Herve ^{[1
]}

Jordaan, Margaritha ^{[2
]}

Meyer, Wolfgang H. ^{[2
]}

Nolan, Steven P. ^{[1
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] Sasol Technol Pty Ltd, R&D Div, ZA-1947 Sasolburg, South Africa

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 01期

关键词：

D O I：

10.1021/jo702169p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The catalytic performances of three Phosphabicyclononane (Phoban)-containing ruthenium-based pre-catalysts have been evaluated for metathesis transformations. A wide screening of substrates in ring-closing metathesis reactions reveals the greater efficiency of pre-catalyst 4. Comparison of the catalytic activities of 4 with Grubbs' first-generation pre-catalyst illustrates the key role of the Phoban ligand. Additionally, a comparative study of three Phoban-containing pre-catalysts has been conducted for the self-metathesis of I-octene at low catalyst loading (25-100 ppm).

引用

页码：259 / 263

页数：5

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