Efficient photoswitching of the nonlinear optical properties of dipolar photochromic Zinc(II) complexes

被引：162

作者：

Aubert, Vincent ^{[1
]}

Guerchais, Veronique ^{[1
]}

Ishow, Elena ^{[2
]}

Hoang-Thi, Khuyen ^{[3
]}

Ledoux, Isabelle ^{[3
]}

Nakatani, Keitaro ^{[2
]}

Le Bozec, Hubert ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France

[2] ENS Cachan, Lab Photophys & Photochim Supramol & Macromol, CNRS, UMR 8531, F-94235 Cachan, France

[3] ENS Cachan, Lab Photon Quant & Mol, CNRS, UMR 8531, F-94235 Cachan, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 03期

关键词：

molecular switches; nonlinear optics; photochromism; zinc;

D O I：

10.1002/anie.200704138

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Flipping the switch: A new type of bipyridine-based ligand functionalized by phenyl- and dimethylaminophenyldithienylethene groups allows the preparation of photochromic dipolar zinc(II) complexes. For the first time, efficient on/off photoswitching of the NLO response of metallochromophores is observed. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：577 / 580

页数：4

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