Syntheses and functions of porous metallosupramolecular networks

被引:388
作者
Suh, Myunghyun Paik [1 ]
Cheon, Young Eun [1 ]
Lee, Eun Young [1 ]
机构
[1] Seoul Natl Univ, Dept Chem, Seoul 151747, South Korea
基金
新加坡国家研究基金会;
关键词
metallosupramolecular networks; metal-organic frameworks; coordination polymers; gas storage; gas separation; guest binding; sensors; macrocyclic complexes; secondary building units; self-assembly; solvothermal reactions; selectivity;
D O I
10.1016/j.ccr.2008.01.032
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Design and synthetic strategies for the construction of porous metallosupramolecular networks are presented. The porous metallosupramolecular networks show various functions such as gas adsorption, molecular recognition, ion exchange, sensing, and production of metal nanoparticles. Their specificities depend on the pore shape, size, and chemical environments of the voids or channels. In this review, relationship between the structures and functions is discussed. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:1007 / 1026
页数:20
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