Ambient temperature reduction of NO to N-2 in Ru-tailored carbon subnanospace

被引：34

作者：

Nishi, Y ^{[1
]}

Suzuki, T ^{[1
]}

Kaneko, K ^{[1
]}

机构：

[1] CHIBA UNIV,FAC SCI,DEPT CHEM,INAGE KU,CHIBA 263,JAPAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 1997年 / 101卷 / 11期

关键词：

D O I：

10.1021/jp963803a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ultrafine Ru particles were dispersed in micropores of activated carbon fiber (ACF). NO was efficiently and rapidly reduced to N-2 on the Ru particles through the disproportionation reaction of 3(NO)(2) = 2 NO2 + 2 N2O in the micropore spaces at 303 K. The N-2 yield at 303 K was 0.8, and the half-life of the reduction reaction was 3 min. The amounts of the byproducts N2O and NO2 on Ru-tailored ACF at 303 K were less than 0.25%. The oxygen was not evolved at 303 K.

引用

页码：1938 / 1939

页数：2

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