Self-assembled diamide nanotubes in organic solvents

被引:61
作者
Díaz, N
Simon, FX
Schmutz, M
Rawiso, M
Decher, G
Jestin, J
Mésini, PJ
机构
[1] Inst Charles Sadron, F-67083 Strasbourg, France
[2] CEA Saclay, Lab Leon Brilloin, F-91191 Gif Sur Yvette, France
关键词
colloids; materials science; nanotubes; self-assembly; supramolecular chemistry;
D O I
10.1002/anie.200500536
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Hydrogen bonding and π-π interactions are the driving forces for the self-assembly of a diamide organogelator into nanotubes in organic solution. Freeze-fracture electron microscopy (see image) and small angle neutron scattering studies show the tubes have a diameter of (24.2 ± 0.3) nm with a wall thickness of (3.3 ± 0.4) nm and an aspect ratio of 1:50 or higher. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:3260 / 3264
页数:5
相关论文
共 40 条
  • [31] Theory of cylindrical tubules and helical ribbons of chiral lipid membranes
    Selinger, JV
    MacKintosh, FC
    Schnur, JM
    [J]. PHYSICAL REVIEW E, 1996, 53 (04) : 3804 - 3818
  • [32] CRYSTALLINE ORDER IN PROBABLY HOLLOW MICELLAR FIBERS OF N-OCTYL-D-GLUCONAMIDE
    SVENSON, S
    KONING, J
    FUHRHOP, JH
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (03) : 1022 - 1028
  • [33] Aqueous suspensions of steroid nanotubules: Structural and rheological characterizations
    Terech, P
    Talmon, Y
    [J]. LANGMUIR, 2002, 18 (19) : 7240 - 7244
  • [34] Low molecular mass gelators of organic liquids and the properties of their gels
    Terech, P
    Weiss, RG
    [J]. CHEMICAL REVIEWS, 1997, 97 (08) : 3133 - 3159
  • [35] Molecular assembly and gelating behavior of didodecanoylamides of α,ω-alkylidenediamines
    Tomioka, K
    Sumiyoshi, T
    Narui, S
    Nagaoka, Y
    Iida, A
    Miwa, Y
    Taga, T
    Nakano, M
    Handa, T
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (47) : 11817 - 11818
  • [36] Biomimetic organization:: Octapeptide self-assembly into nanotubes of viral capsid-like dimension
    Valéry, C
    Paternostre, M
    Robert, B
    Gulik-Krzywicki, T
    Narayanan, T
    Dedieu, JC
    Keller, G
    Torres, ML
    Cherif-Cheikh, R
    Calvo, P
    Artzner, F
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2003, 100 (18) : 10258 - 10262
  • [37] Organic templates for the generation of inorganic materials
    van Bommel, KJC
    Friggeri, A
    Shinkai, S
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (09) : 980 - 999
  • [38] Molecular self-assembly of surfactant-like peptides to form nanotubes and nanovesicles
    Vauthey, S
    Santoso, S
    Gong, HY
    Watson, N
    Zhang, SG
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) : 5355 - 5360
  • [39] MOLECULAR SELF-ASSEMBLY AND NANOCHEMISTRY - A CHEMICAL STRATEGY FOR THE SYNTHESIS OF NANOSTRUCTURES
    WHITESIDES, GM
    MATHIAS, JP
    SETO, CT
    [J]. SCIENCE, 1991, 254 (5036) : 1312 - 1319
  • [40] Lipid nanotubes as substrates for helical crystallization of macromolecules
    Wilson-Kubalek, EM
    Brown, RE
    Celia, H
    Milligan, RA
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1998, 95 (14) : 8040 - 8045