Atomic structure of chemisorbed iodine layer on Cu(110)

被引:22
作者
Andryushechkin, BV [1 ]
Eltsov, KN [1 ]
Shevlyuga, VM [1 ]
机构
[1] Russian Acad Sci, AM Prokhorov Gen Phys Inst, Ctr Nat Sci Res, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
scanning tunnelling microscopy; surface structure; chemisorption; phase transitions; copper; iodine;
D O I
10.1016/j.susc.2005.04.009
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The adsorption of iodine on Cu(110) has been studied with scanning tunnelling microscopy and low energy electron diffraction. A simple commensurate structure c(2 x 2) is formed at the coverage 0 = 0.5 ML. Further adsorption of iodine leads to the uniaxial compression of the c(2 x 2) structure along [110] direction of the substrate. STM data show that the compression includes the formation and development of striped domain walls. At the saturation point (0 = 0.63 ML), iodine forms a uniformly compressed quasi-hexagonal structure, (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:278 / 286
页数:9
相关论文
共 24 条
[1]   CuI growth on copper surfaces under molecular iodine action: influence of the surface anisotropy in the iodine monolayer [J].
Andryushechkin, BV ;
Eltsov, KN ;
Shevlyuga, VM .
SURFACE SCIENCE, 2004, 566 :203-209
[2]   Structural transitions of chemisorbed iodine on Cu(100) [J].
Andryushechkin, BV ;
Eltsov, KN ;
Shevlyuga, VM ;
Bardi, U ;
Cortigiani, B .
SURFACE SCIENCE, 2002, 497 (1-3) :59-69
[3]   Atomic scale observation of iodine layer compression on Cu(111) [J].
Andryushechkin, BV ;
Eltsov, KN ;
Shevlyuga, VM .
SURFACE SCIENCE, 2001, 472 (1-2) :80-88
[4]  
[Anonymous], 1992, 2 DIMENSIONAL CRYSTA
[6]   LEED, AES AND THERMAL-DESORPTION STUDY OF IODINE CHEMISORPTION ON THE SILVER(100), SILVER(111) AND SILVER(110) FACES [J].
BARDI, U ;
ROVIDA, G .
SURFACE SCIENCE, 1983, 128 (01) :145-168
[7]   Structure of the c(2x2)-Br/Pt(110) surface -: art. no. 165408 [J].
Blum, V ;
Hammer, L ;
Heinz, K ;
Franchini, C ;
Redinger, J ;
Swamy, K ;
Deisl, C ;
Bertel, E .
PHYSICAL REVIEW B, 2002, 65 (16)
[8]   VAN DER WAALS VOLUMES + RADII [J].
BONDI, A .
JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+
[9]  
BUSHEL J, 2005, IN PRESS J PHYS CH B
[10]   EXPLICIT PERIODIC TREND OF VANDERWAALS RADII [J].
CHAUVIN, R .
JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (23) :9194-9197