CuI growth on copper surfaces under molecular iodine action: influence of the surface anisotropy in the iodine monolayer

被引：24

作者：

Andryushechkin, BV ^{[1
]}

Eltsov, KN ^{[1
]}

Shevlyuga, VM ^{[1
]}

机构：

[1] Russian Acad Sci, AM Prokhorov Gen Phys Inst, Ctr Nat Sci Res, Moscow 119991, Russia

来源：

SURFACE SCIENCE | 2004年 / 566卷

关键词：

scanning tunneling microscopy; surface structure; morphology; roughness; and topography; interface states; halides; copper; iodine;

D O I：

10.1016/j.susc.2004.05.045

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Halide nucleation and growth on monocrystalline copper substrates under molecular halogens action was studied by means of Auger Electron Spectroscopy (AES) and Scanning Tunnelling Microscopy (STM). It was found that copper iodide grows on Cu(1 0 0) and Cu(1 1 1) in a layer-by-layer mode with its outer hexagonal plane parallel to the substrate surface. The STM images of copper iodide demonstrate Moire-like superstructures. The nature of these superstructures is explained in terms of superposition of the copper iodide layer and the underlying "interface" monolayer. It was found that the interface layer preserves geometrical and electronic structure of the saturated chemisorbed iodine monolayer for both copper planes. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：203 / 209

页数：7

共 9 条

[1] Direct STM observation of surface modification and growth of AgCl islands on Ag(111) upon chlorination at room temperature [J].

Andryushechkin, BV ;

Eltsov, KN ;

Shevlyuga, VM ;

Yurov, VY .

SURFACE SCIENCE, 1999, 431 (1-3) :96-108

[2]

Andryushechkin BV, 2003, PHYS LOW-DIMENS STR, V3-4, P1

[3] Structural transitions of chemisorbed iodine on Cu(100) [J].

Andryushechkin, BV ;

Eltsov, KN ;

Shevlyuga, VM ;

Bardi, U ;

Cortigiani, B .

SURFACE SCIENCE, 2002, 497 (1-3) :59-69

[4] Domain-wall mechanism of "(n√3 x n√3)R30°" incommensurate structure formation in chemisorbed halogen layers on Cu(111) [J].

Andryushechkin, BV ;

Eltsov, KN ;

Shevlyuga, VM .

SURFACE SCIENCE, 2000, 470 (1-2) :L63-L68

[5] Atomic scale observation of iodine layer compression on Cu(111) [J].

Andryushechkin, BV ;

Eltsov, KN ;

Shevlyuga, VM .

SURFACE SCIENCE, 2001, 472 (1-2) :80-88

[6]

Ashcroft N.W., 1976, Solid State Physics

[7]

Eltsov K. N., 1996, PHYS LOW-DIMENS STR, V9-10, P7

[8]

ELTSOV KN, 1996, PHYS LOW-DIMENS STR, V7, P15

[9]

Malinowski E., 1980, FACTOR ANAL CHEM

← 1 →