An octane-fueled olid oxide fuel cell

被引:503
作者
Zhan, ZL [1 ]
Barnett, SA [1 ]
机构
[1] Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA
关键词
D O I
10.1126/science.1109213
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
There are substantial barriers to the introduction of hydrogen fuel cells for transportation, including the high cost of fuel-cell systems, the current tack of a hydrogen infrastructure, and the relatively low fuel efficiency when using hydrogen produced from hydrocarbons. Here, we describe a solid oxide fuel cell that combines a catalyst layer with a conventional anode, allowing internal reforming of iso-octane without coking and yielding stable power densities of 0.3 to 0.6 watts per square centimeter. This approach is potentially the basis of a simple low-cost System that can provide substantially higher fuel efficiency by using excess fuel-cell heat for the endothermic reforming reaction.
引用
收藏
页码:844 / 847
页数:4
相关论文
共 22 条
[1]   Kinetics of internal steam reforming of methane on Ni/YSZ-based anodes for solid oxide fuel cells [J].
Ahmed, K ;
Foger, K .
CATALYSIS TODAY, 2000, 63 (2-4) :479-487
[2]   PARTIAL OXIDATION OF METHANE TO SYNTHESIS GAS-USING CARBON-DIOXIDE [J].
ASHCROFT, AT ;
CHEETHAM, AK ;
GREEN, MLH ;
VERNON, PDF .
NATURE, 1991, 352 (6332) :225-226
[3]   Advanced anodes for high-temperature fuel cells [J].
Atkinson, A ;
Barnett, S ;
Gorte, RJ ;
Irvine, JTS ;
Mcevoy, AJ ;
Mogensen, M ;
Singhal, SC ;
Vohs, J .
NATURE MATERIALS, 2004, 3 (01) :17-27
[4]  
BOSSEL U, 2003, E08 EUR FUEL CELL FO
[5]  
BOTTI J, 2003, P 8 INT S SOL OX FUE, P16
[6]  
DEVITT J, 2003, P 8 INT S SOL OX FUE, P1276
[7]  
GEORGE R, 2002, 2002 FUEL CELL SEM W, P977
[8]   Novel SOFC anodes for the direct electrochemical oxidation of hydrocarbons [J].
Gorte, RJ ;
Vohs, JM .
JOURNAL OF CATALYSIS, 2003, 216 (1-2) :477-486
[9]   Novel SOFC anodes for the direct electrochemical oxidation of hydrocarbon [J].
Gorte, RJ ;
Kim, H ;
Vohs, JM .
JOURNAL OF POWER SOURCES, 2002, 106 (1-2) :10-15
[10]  
LIN Y, UNPUB SOLID STATE IO