Lewis base functionalised cyclopentadienyl complexes of titanium

被引：26

作者：

Hughes, AK

Marsh, SMB

Howard, JAK

Ford, PS

机构：

[1] Department of Chemistry, University Science Laboratories, Durham DH1 3LE, South Road

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 528卷 / 1-2期

关键词：

titanium; cyclopentadienyl; imide; amide; crystal structure;

D O I：

10.1016/S0022-328X(96)06518-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Ti(NMe(2))(4) with the amine functionalised cyclopentadiene C5H5CH2CH2CH2N(H)CMe(3) gives the titanium cyclopentadienyl-amide complex [Ti(eta(5):sigma(1)-(C(5)H(4)CH(2)CH(2)CH(2)NCMe(3))}(NMe(2))(2)] which reacts with aniline to generate the phenylimido bridged dimer [{Ti(eta(5)-C5H4CH2CH2CH2N(H)CMe(3))(NHPh))(2)(mu-NPh)(2)] whose molecular structure has been determined by X-ray diffraction, revealing a slightly asymmetric Ti(mu-NPh)(2)Ti core.

引用

页码：195 / 198

页数：4