Toward the creation of NMR databases in chiral solvents for assignments of relative and absolute stereochemistry: NMR desymmetrization of meso compounds

被引：29

作者：

Kobayashi, Y ^{[1
]}

Hayashi, N ^{[1
]}

Kishi, Y ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 14期

关键词：

D O I：

10.1021/ol010110q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(Matrix presented) Examples of 13C NMR desymmetrization of meso compounds are presented. On analysis of the NMR profiles of 1,3-diols, the additivity is recognized to predict the NMR profiles of 1,3,5-tirols.

引用

页码：2253 / 2255

页数：3

共 4 条

[1] Toward the creation of NMR databases in chiral solvents for assignments of relative and absolute stereochemistry: Scope and limitation [J].

Hayashi, N ;

Kobayashi, Y ;

Kishi, Y .

ORGANIC LETTERS, 2001, 3 (14) :2249-2252

[2] USE OF CHIRAL SOLVENTS OR LANTHANIDE SHIFT REAGENTS TO DISTINGUISH MESO FROM D OR L DIASTEREOMERS [J].

KAINOSHO, M ;

BEARE, SD ;

AJISAKA, K ;

PIRKLE, WH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (16) :5924-&

[3]

Kobayashi Y, 2000, HELV CHIM ACTA, V83, P2562, DOI 10.1002/1522-2675(20000906)83:9<2562::AID-HLCA2562>3.0.CO

[4]

2-Z

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