Toward the creation of NMR databases in chiral solvents for assignments of relative and absolute stereochemistry: Scope and limitation

被引：30

作者：

Hayashi, N ^{[1
]}

Kobayashi, Y ^{[1
]}

Kishi, Y ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 14期

关键词：

D O I：

10.1021/ol010109r

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

[GRAPHICS] Three additional NMR databases, 1-3, in a chiral solvent are presented. The C.21-C.38 portion of oasomycin A is used to demonstrate the scope and limitation of the universal NMR database approach in a chiral solvent for assignment of relative and absolute stereochemistry without degradation and/or derivatization.

引用

页码：2249 / 2252

页数：4

共 10 条

[1]

C-13 NMR-STUDY OF ALPHA-ANOMERIC AND BETA-ANOMERIC PAIRS OF D-MANNOPYRANOSIDES AND L-RHAMNOPYRANOSIDES [J].

KASAI, R ;

OKIHARA, M ;

ASAKAWA, J ;

MIZUTANI, K ;

TANAKA, O .

TETRAHEDRON, 1979, 35 (11) :1427-1432

[2]

Kobayashi Y, 2000, ANGEW CHEM INT EDIT, V39, P4279, DOI 10.1002/1521-3773(20001201)39:23<4279::AID-ANIE4279>3.0.CO

[3]

2-R

[4]

Kobayashi Y, 2000, HELV CHIM ACTA, V83, P2562, DOI 10.1002/1522-2675(20000906)83:9<2562::AID-HLCA2562>3.0.CO

[5]

2-Z

[6]

Toward the creation of NMR databases in chiral solvents for assignments of relative and absolute stereochemistry: NMR desymmetrization of meso compounds [J].

Kobayashi, Y ;

Hayashi, N ;

Kishi, Y .

ORGANIC LETTERS, 2001, 3 (14) :2253-2255

[7]

Toward creation of a universal NMR database for stereochemical assignment: Complete structure of the desertomycin/oasomycin class of natural products [J].

Kobayashi, Y ;

Tan, CH ;

Kishi, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (09) :2076-2078

[8]

KOBAYASHI Y, 2001, ORG LETT, V3

[9]

Tan CH, 2000, ANGEW CHEM INT EDIT, V39, P4282, DOI 10.1002/1521-3773(20001201)39:23<4282::AID-ANIE4282>3.0.CO

[10]

2-U

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