Perfluorocarbon-hydrocarbons self-assembly: halogen bonding mediated intermolecular recognition

被引：69

作者：

Fox, DB

Liantonio, R

Metrangolo, P

Pilati, T

Resnati, G

机构：

[1] Politecn Milan, Dept Chem Mat & Chem Engn G Natta, I-20131 Milan, Italy

[2] CNR, Inst Mol Sci & Technol, I-20133 Milan, Italy

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2004年 / 125卷 / 02期

关键词：

halogen bonding; fluorine; iodine; supramolecular chemistry; self-assembly;

D O I：

10.1016/j.jfluchem.2003.07.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Halogen bonding is discussed as an interaction that is capable of overcoming the reluctance shown by fluorinated compounds towards interactions with hydrocarbons. This non-covalent interaction is sufficiently strong to enact formation of supramolecular architectures where perfluorocarbons, hydrocarbons, and inorganic salts are self-assembled. Examples are discussed which exemplify the consistency and versatility of this interaction in affording numerous and structurally different hybrid materials. The importance of fluorine in determining the overall packing of the formed architectures is also highlighted. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：271 / 281

页数：11

共 72 条

[41] DONOR-ACCEPTOR COMPLEXES FORMED BY PERFLUORO-ORGANO BROMIDES AND IODIDES WITH NITROGENOUS AND OTHER BASES .5. COMPARISON OF LIQUID-PHASE COMPLEXES OF CFI3, C2F5I OR C3F7I WITH NME3, NET3 OR NPR3 - INFRARED, FAR-INFRARED AND NMR-SPECTRA [J].