Molten salts near a charged surface: integral equation approximation for a model of KCl

被引：14

作者：

Booth, MJ

Haymet, ADJ

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

[2] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

MOLECULAR PHYSICS | 2001年 / 99卷 / 21期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1080/00268970110075167

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A study has been made of the electrical 'double layer' structure of molten salts, in particular a model of molten potassium chloride, using an integral equation approximation. This is in contrast to most statistical mechanical treatments of the double layer, which have concentrated on aqueous elecrolyte solutions. The results are compared with the output of computer simulations. In addition to the structural information contained in the density profiles, the calculations yielded charge profiles, the mean electrostatic potential and the double layer capacitance.

引用

收藏

页码：1817 / 1824

页数：8

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