Functionalized graphene and graphene oxide solution via polyacrylate coating

被引：72

作者：

Saha, Arindam ^{[2
]}

Basiruddin, S. K. ^{[2
]}

Ray, S. C. ^{[1
]}

Roy, S. S. ^{[3
]}

Jana, Nikhil R. ^{[2
]}

机构：

[1] Univ Witwatersrand, Sch Phys, Johannesburg, South Africa

[2] Indian Assoc Cultivat Sci, Ctr Adv Mat, Kolkata 700032, India

[3] Univ Ulster, Sch Engn, Nanotechnol & Integrated Bioengn Ctr, Newtownabbey BT37 0QB, North Ireland

来源：

NANOSCALE | 2010年 / 2卷 / 12期

关键词：

LIQUID-PHASE EXFOLIATION; NANOPARTICLES; REDUCTION; GRAPHITE; NANORODS; POLYMER; SHEETS; NANOCOMPOSITES; TRANSPARENT; CHEMISTRY;

D O I：

10.1039/c0nr00376j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Water soluble graphene with various chemical- and biofunctionalities is essential for their different applications. However, exfoliated graphenes are insoluble in water and water soluble graphene oxide precipitate if they are chemically reduced to graphene. We have developed a polyacrylate coating method for graphene oxide and then chemically reduced it into graphene. We found that polyacrylate coating can improve the colloidal stability of both graphene and graphene oxide. The coated graphene has been characterized using XPS, FTIR, XRD and micro-Raman spectroscopy. The primary amine present on the coating backbone has been used to derive glucose functionalized water soluble graphene. Various other functional graphenes can be anticipated from the polyacrylate coated graphene.

引用

页码：2777 / 2782

页数：6

共 52 条

[1] Advances in Coating Chemistry in Deriving Soluble Functional Nanoparticle [J].

Basiruddin, S. K. ;

Saha, Arindam ;

Pradhan, Narayan ;

Jana, Nikhil R. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (25) :11009-11017

[2] Functionalized Gold Nanorod Solution via Reverse Micelle Based Polyacrylate Coating [J].

Basiruddin, S. K. ;

Saha, Arindam ;

Pradhan, Narayan ;

Jana, Nikhil R. .

LANGMUIR, 2010, 26 (10) :7475-7481

[3] Liquid-Phase Exfoliation of Graphite Towards Solubilized Graphenes [J].

Bourlinos, Athanasios B. ;

Georgakilas, Vasilios ;

Zboril, Radek ;

Steriotis, Theodore A. ;

Stubos, Athanasios K. .

SMALL, 2009, 5 (16) :1841-1845

[4] Preparation of graphene by a low-temperature thermal reduction at atmosphere pressure [J].

Chen, Wufeng ;

Yan, Lifeng .

NANOSCALE, 2010, 2 (04) :559-563

[5] Stable dispersions of graphene and highly conducting graphene films: a new approach to creating colloids of graphene monolayers [J].

Chen, Yao ;

Zhang, Xiong ;

Yu, Peng ;

Ma, Yanwei .

CHEMICAL COMMUNICATIONS, 2009, (30) :4527-4529

[6] Flexible, Transparent, Conducting Films of Randomly Stacked Graphene from Surfactant-Stabilized, Oxide-Free Graphene Dispersions [J].

De, Sukanta ;

King, Paul J. ;

Lotya, Mustafa ;

O'Neill, Arlene ;

Doherty, Evelyn M. ;

Hernandez, Yenny ;

Duesberg, Georg S. ;

Coleman, Jonathan N. .

SMALL, 2010, 6 (03) :458-464

[7] Preparation and characterization of graphene oxide paper [J].

Dikin, Dmitriy A. ;

Stankovich, Sasha ;

Zimney, Eric J. ;

Piner, Richard D. ;

Dommett, Geoffrey H. B. ;

Evmenenko, Guennadi ;

Nguyen, SonBinh T. ;

Ruoff, Rodney S. .

NATURE, 2007, 448 (7152) :457-460

[8] The chemistry of graphene oxide [J].

Dreyer, Daniel R. ;

Park, Sungjin ;

Bielawski, Christopher W. ;

Ruoff, Rodney S. .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240

[9] The rise of graphene [J].

Geim, A. K. ;

Novoselov, K. S. .

NATURE MATERIALS, 2007, 6 (03) :183-191

[10] High-Yield Organic Dispersions of Unfunctionalized Graphene [J].

Hamilton, Christopher E. ;

Lomeda, Jay R. ;

Sun, Zhengzong ;

Tour, James M. ;

Barron, Andrew R. .

NANO LETTERS, 2009, 9 (10) :3460-3462

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