Incorporation of chemical functionalities in the framework of mesoporous silica

被引:108
作者
Linares, Noemi [2 ]
Serrano, Elena [2 ]
Rico, Marisa [2 ]
Mariana Balu, Alina [1 ]
Losada, Elia [1 ]
Luque, Rafael [1 ]
Garcia-Martinez, Javier [2 ]
机构
[1] Univ Cordoba, Dept Quim Organ, E-14014 Cordoba, Spain
[2] Univ Alicante, Mol Nanotechnol Lab, E-03080 Alicante, Spain
关键词
MOLECULAR-SIEVES; ANIONIC SURFACTANT; CATALYTIC-ACTIVITY; GOLD NANOPARTICLES; CONTROLLED-RELEASE; TEMPLATING ROUTE; PD NANOPARTICLES; HYBRID MATERIALS; METAL-COMPLEXES; ORGANIC GROUPS;
D O I
10.1039/c1cc11016k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mesoporous silica, which shows well-defined pore systems, tunable pore diameters (2-30 nm), narrow pore size distributions and high surface areas (>600 m(2) g(-1)), is frequently modified using different methodologies (including in situ and post-synthetic strategies) to introduce various chemical functionalities useful in applications like catalysis, separation, drug delivery, and sensing. This contribution aims to provide a critical overview of the various strategies to incorporate chemical functionalities in mesoporous silica highlighting the advantages of the in situ methods based on the bottom-up construction of mesoporous silica containing various chemical functionalities in its structure.
引用
收藏
页码:9024 / 9035
页数:12
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